Optimizing solid electrolyte interphase on graphite anode by adjusting the electrolyte solution structure with ionic liquid

Date Published
01/2018
Publication Type
Journal Article
Authors
DOI
10.1016/j.electacta.2017.12.009
Abstract

N-allyl-N-methylpiperidinium bis(trifuoromethansulfonyl)imide (PP13*TFSI) ionic liquid was adopted as a solute replacing partial of lithium salt in a concentrated propylene carbonate (PC) electrolyte. Varying the concentration of PP13*TFSI ionic liquid can change the electrolyte solution structure and thus optimize the solid electrolyte interphase (SEI) on the graphite anode. The number of PC molecules coordinated with lithium ion is significantly altered and this results in a change of the SEI mechanism at the electrode/electrolyte interface. At an optimum molar ratio of 2:1 between LiTFSI and PP13*TFSI, the first coulombic efficiency and the cycling capability of the graphite anode are significantly improved. Fourier transform infrared spectroscopy (FTIR) verified the SEI mechanism change from two-electron reduction to one-electron reduction in the presence of PP13*TFSI ionic liquid. SEM and TEM observations reveal a thin, homogenous and compact SEI film formed on the graphite surface in the 3 mol L−1 LiTFSI+PP13*TFSI(2:1)/PC concentrated electrolyte.

Journal
Electrochimica Acta
Volume
260
Year of Publication
2018
Pagination
640 - 647
ISSN Number
00134686
Short Title
Electrochimica Acta
Refereed Designation
Refereed
Organizations
Research Areas
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