Efficient hydrogen peroxide generation using reduced graphene oxide-based oxygen reduction electrocatalysts

Date Published
03/2018
Publication Type
Journal Article
Authors
DOI
10.1038/s41929-018-0044-2
Abstract

Electrochemical oxygen reduction has garnered attention as an emerging alternative to the traditional anthraquinone oxidation process to enable the distributed production of hydrogen peroxide. Here, we demonstrate a selective and efficient non-precious electrocatalyst, prepared through an easily scalable mild thermal reduction of graphene oxide, to form hydrogen peroxide from oxygen. During oxygen reduction, certain variants of the mildly reduced graphene oxide electrocatalyst exhibit highly selective and stable peroxide formation activity at low overpotentials (<10 mV) under basic conditions, exceeding the performance of current state-of-the-art alkaline catalysts. Spectroscopic structural characterization and in situ Raman spectroelectrochemistry provide strong evidence that sp2-hybridized carbon near-ring ether defects along sheet edges are the most active sites for peroxide production, providing new insight into the electrocatalytic design of carbon-based materials for effective peroxide production.

Journal
Nature Catalysis
Volume
1
Year of Publication
2018
Issue
4
Pagination
282 - 290
Short Title
Nat Catal
Refereed Designation
Refereed
Organizations
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