Controlled synthesis and size-dependent polarization domain structure of colloidal germanium telluride nanocrystals
Publication Type | Journal Article
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Authors | |
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DOI |
10.1021/ja108309s
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Abstract |
Germanium telluride (GeTe) exhibits interesting materials properties, including a reversible amorphous-to-crystalline phase transition and a room-temperature ferroelectric distortion, and has demonstrated potential for nonvolatile memory applications. Here, a colloidal approach to the synthesis of GeTe nanocrystals over a wide range of sizes is demonstrated. These nanocrystals have size distributions of 10-20% and exist in the rhombohedral structure characteristic of the low-temperature polar phase. The production of nanocrystals of widely varying sizes is facilitated by the use of Ge(II) precursors with different reactivities. A transition from a monodomain state to a state with multiple polarization domains is observed with increasing size, leading to the formation of richly faceted nanostructures. These results provide a starting point for deeper investigation into the size-scaling and fundamental nature of polar-ordering and phase-change processes in nanoscale systems. © 2011 American Chemical Society.
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Notes |
cited By 40
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Journal |
Journal of the American Chemical Society
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Volume |
133
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Year of Publication |
2011
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Number |
7
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Pagination |
2044-2047
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ISSN Number |
00027863
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Keywords |
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Research Areas | |
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