%0 Journal Article
%A Wei Tong
%A Glenn G Amatucci
%B Journal of Power Sources
%D 2017
%G eng
%P 86 - 91
%R 10.1016/j.jpowsour.2017.07.008
%T Silver copper fluoride: A novel perovskite cathode for lithium batteries
%V 362
%8 09/2017
%! Journal of Power Sources
%X <p><span>An electrochemically active nanostructured silver copper&nbsp;<a title="Learn more about Fluoride from ScienceDirect's AI-generated Topic Pages" href="https://www.sciencedirect.com/topics/chemistry/fluoride">fluoride</a><span>&nbsp;(SCF)&nbsp;<a title="Learn more about Perovskites from ScienceDirect's AI-generated Topic Pages" href="https://www.sciencedirect.com/topics/chemistry/perovskites">perovskite</a>, AgCuF</span></span><span>3</span><span>, was synthesized&nbsp;</span><em>via</em><span>&nbsp;a mechanochemical reaction between AgF and CuF</span><span>2</span><span>&nbsp;precursors. Phase composition and&nbsp;<a title="Learn more about Electrochemical Property from ScienceDirect's AI-generated Topic Pages" href="https://www.sciencedirect.com/topics/materials-science/electrochemical-property">electrochemical properties</a>&nbsp;of the SCF perovskites produced under various synthetic parameters were studied. The optimum SCF perovskite sample exhibited an appreciable electrochemical performance through the use of conductive carbon matrix in a primary lithium half cell. A high specific capacity of 270&nbsp;mAh&nbsp;g</span><span>−1</span><span>&nbsp;was achieved at a cutoff voltage of 2&nbsp;V with 190&nbsp;mAh&nbsp;g</span><span>−1</span><span>&nbsp;above 3&nbsp;V, leading to a total volumetric energy density of 3666&nbsp;Wh&nbsp;L</span><span>−1</span><span>&nbsp;at &gt;3&nbsp;V and 4848&nbsp;Wh&nbsp;L</span><span>−1</span><span>&nbsp;at &gt;2&nbsp;V.</span></p>