%0 Journal Article %K Superconducting materials %K Laser Beams–Applications %K Stacking Defects %K Superconducting Films–Thin Films %K Yttrium Compounds–Thin Films %K Cationic Vacancy Ordered Defect Structure %K Laser-Deposited Thin Films %K Yttrium Barium Copper Oxide Thin Films %A Ramamoorthy Ramesh %A T.S Ravi %A D.M Hwang %A A Inam %A X.X Xi %A X.D Wu %A T Venkatesan %A R Kilaas %B Materials Letters %D 1990 %G eng %P 23-27 %R 10.1016/0167-577X(90)90006-8 %T Direct observation of a new cationic vacancy ordered defect structure in laser-deposited superconducting YBaCuO thin films %V 10 %X The Y2Ba4Cu8O16 phase is the most common stacking defect observed in laser-deposited YBaCuO thin films. In this we report for the fist time, the existence of a cationic vacancy ordered Y2Ba4Cu8O16 structure in which every alternate pair of Cu atoms in the two chain layers are missing. This new structure is a polytype of the Y1Ba2Cu3O7 phase, i.e. it has the "Y2Ba4Cu8O16" structure but the "Y1Ba2Cu3O7" composition. Some possible causes and consequences of the formation of this defect structure are discussed. © 1990.