%0 Journal Article %K thin films %K ablation %K superconducting films %K scanning electron microscopy %K pulsed laser ablation %K crystal growth %K Ferroelectric materials %K High temperature superconductors %K Interfaces (materials) %K Laser pulses %K Crystal microstructure %K X ray spectroscopy %K Lead titanate thin films %K Thermal expansion mismatch %A S.G Ghonge %A E Goo %A Ramamoorthy Ramesh %B Applied Physics Letters %D 1993 %G eng %P 1742-1744 %R 10.1063/1.109592 %T Microstructure of c-axis oriented lead titanate thin films by pulsed laser ablation %V 62 %X Epitaxial ferroelectric PbTiO3/YBa2Cu 3O7-x heterostructures have been fabricated on [001] LaAlO3 by pulsed laser ablation. X-ray diffractometer scans showed only the (00l) peaks from the lead titanate and YBa2Cu 3O7-x film indicating c-axis growth. Transmission electron microscopy on planar and cross-sectional samples revealed a single domain film. The c-axis orientation in the lead titanate film is ascribed to the good lattice match of the a-axis of lead titanate with the a- or b-axes of the YBa2Cu3O7-x film. A cubic lead titanate film is deposited above the Curie point. Compressive stresses arise in the lead titanate film due to lattice mismatch. The c-axis orientation is favored since it reduces the compressive residual stresses.