%0 Journal Article %K thin films %K film growth %K Ferroelectric materials %K Doping (additives) %K Lead compounds %K Doppler effect %K Positron annihilation %A T Fhessnegg %A S Aggarwal %A B Nielsen %A Ramamoorthy Ramesh %A D.J Keeble %A E.H Poindcxtor %B IEEE Transactions on Ultrasonics, Ferroelectrics, and Frequency Control %D 2000 %G eng %P 916-920 %R 10.1109/58.852074 %T A study of vacancy-related defects in (pb,la)(zr,ti)o3 thin films using positron annihilation %V 47 %X The formation of vacancy-type defects in La-doped lead zirconate titanato (PLZT) thin films (Zr/Ti=20/80) was studied as a function of lanthanum doping and after cooling in an oxygen-reduced ambient. The changes in the Doppler-broadening S parameter are consistent with the progressive introduction of Pb-vacancies upon La-doping. Cooling of PLZT thin films with 0 and 10% La doping in 10-5 Torr oxygen partial pressure after growth exhibits am increase in the density of vacancy-type defects compared to films cooled in 760 Torr. It is proposed that the defects formed are likely cation-oxygen vacancy complexes. © 2000 IEEE.