%0 Journal Article %K pulsed laser deposition %K transmission electron microscopy %K Perovskite %K lattice constants %K electrodes %K Ferroelectric materials %K Epitaxial growth %K Heterojunctions %K Capacitors %K Compressive strain %K Thick films %K Electrostatics %K Ultrathin films %K Lattice mismatch %K Pulsed polarization %K Switched polarization %K Cathode ray oscilloscopes %K Photoresists %K Superconducting transition temperature %A V Nagarajan %A S Prasertchoung %A T Zhao %A H Zheng %A J Ouyang %A Ramamoorthy Ramesh %A W Tian %A X.Q Pan %A D.M Kim %A C.B Eom %A H Kohlstedt %A R Waser %B Applied Physics Letters %D 2004 %G eng %P 5225-5227 %R 10.1063/1.1765742 %T Size effects in ultrathin epitaxial ferroelectric heterostructures %V 84 %X The thickness scaling effect in PbZr 0.2Ti 0.8O 3 heterostructures was investigated. A systematic quantitative experimental study of the thickness dependence of switched polarization in (001) epitaxial PZT films, 4 to 80 nm thick was also shown. The experiment was focused on the PZT composition since it had an in-plane lattice parameter. A preliminary model based on a modified Landau Ginzburg approach suggested that the nature of the electrostatics at the ferroelectric-electrode interface played a significant role in the scaling of ferroelectric thin films.