%0 Journal Article %K film growth %K crystal structure %K Crystallography %K bismuth compounds %K ferroelectricity %K Ferroelectric domain structure %K Polarization direction %K Piezoelectric force microscopy %K Light polarization %K In-plane piezoresponse %K Cantilever beams %A F Zavaliche %A R.R Das %A D.M Kim %A C.B Eom %A S.Y Yang %A P Shafer %A Ramamoorthy Ramesh %B Applied Physics Letters %D 2005 %G eng %P 1-3 %R 10.1063/1.2126804 %T Ferroelectric domain structure in epitaxial BiFeO 3 films %V 87 %X Piezoelectric force microscopy is employed to study the ferroelectric domain structure in a 600 nm thick epitaxial BiFe O3 film. In the as-grown film, a mosaic-like domain structure is observed. Scans taken with the cantilever pointing along the principal crystallographic directions enabled us to reconstruct the polarization direction. By combining the perpendicular and in-plane piezoresponse data, we found that the ferroelectric domain structure is mainly described by four polarization directions. These directions point oppositely along two body diagonals, which form an angle of ∼71°. The other variants are also occasionally observed. © 2005 American Institute of Physics.