%0 Journal Article %K thin films %K electron microscopy %K Polarization %K Epitaxial growth %K polarization switching %K bismuth compounds %K ferroelectricity %K Strontium compounds %K Ferroelectric domain structure %K Piezoelectric force microscopy %K Piezoresponse data %K Vectors %A F Zavaliche %A P Shafer %A Ramamoorthy Ramesh %A M.P Cruz %A R.R Das %A D.M Kim %A C.B Eom %B Applied Physics Letters %D 2005 %G eng %P 1-3 %R 10.1063/1.2149180 %T Polarization switching in epitaxial BiFeO 3 films %V 87 %X Ferroelectric domain structure and polarization switching in an epitaxial BiFe O3 film grown on a 0.8° miscut SrTi O3 (001) substrate were studied by piezoelectric force microscopy. The film shows a two-domain stripe pattern, with the polarization vectors oriented along two 〈111〉 axes which form an angle of 71°. Polarization switching was investigated by locally poling the film. By combining the perpendicular and in-plane piezoresponse data we found that polarization rotates by 71° and 109°, while 180° switching is mainly observed at low fields. © 2005 American Institute of Physics.