%0 Journal Article %K nanostructured materials %K hysteresis %K heterostructures %K Domain walls %K Ferroelectric materials %K multiferroic %K exchange bias %K ferroelectricity %K Ferroelectric domains %K X ray crystallography %K Dichroism %K Coercive force %K Cobalt %K Magnetic domains %K Semiconducting bismuth compounds %K Domain structures %K Nanoscale controls %K Piezoresponse force microscopies %K Magnetic thin films %K Crystals %K Coercive fields %K Exchange enhancements %K Large shifts %K Nano-scale %K X-ray magnetic circular dichroisms %A L.W Martin %A Y.-H Chu %A M.B Holcomb %A M Huijben %A P Yu %A S.-J Han %A D Lee %A S.X Wang %A Ramamoorthy Ramesh %B Nano Letters %D 2008 %G eng %P 2050-2055 %R 10.1021/nl801391m %T Nanoscale control of exchange bias with BiFeO 3 thin films %V 8 %X We demonstrate a direct correlation between the domain structure of multiferroic BiFeO 3 thin films and exchange bias of Co 0.9Fe 0.1/BiFeO 3 heterostructures. Two distinct types of interactions - an enhancement of the coercive field (exchange enhancement) and an enhancement of the coercive field combined with large shifts of the hysteresis loop (exchange bias) - have been observed in these heterostructures, which depend directly on the type and crystallography of the nanoscale (∼2 nm) domain walls in the BiFeO 3 film. We show that the magnitude of the exchange bias interaction scales with the length of 109° ferroelectric domain walls in the BiFeO 3 thin films which have been probed via piezoresponse force microscopy and X-ray magnetic circular dichroism. © 2008 American Chemical Society.