%0 Journal Article %K Nanostructured materials %K Domain walls %K Electrostatic boundary conditions %K Periodic structures %K Bottom electrodes %K Walls (structural partitions) %K Semiconducting bismuth compounds %K Anisotropic strains %K Domain architectures %K Domain structures %K La-substituted %K Nanoscale arrays %K Nanoscale controls %K One-dimensional %K Periodic domains %K Piezoresponse force microscopies %K Poling effects %K Single-crystal substrates %K X-ray diffractions %A Y.-H Chu %A Q He %A C.-H Yang %A P Yu %A L.W Martin %A P Shafer %A Ramamoorthy Ramesh %B Nano Letters %D 2009 %G eng %P 1726-1730 %R 10.1021/nl900723j %T Nanoscale control of domain architectures in BiFeO 3 thin films %V 9 %X We demonstrate an approach to create a one-dimensional nanoscale array of domain walls in epitaxial La-substituted BiFeO 3 films. We have used a DyScO 3 (110) o single-crystal substrate to provide an anisotropic strain to exclude two of the possible structural variants. Furthermore, through careful control of electrostatic boundary conditions, such as the thickness of the SrRuO 3 bottom electrode to induce the self-poling effects, we can choose to obtain either 109° or 71° one-dimensional periodic domain walls. Detailed measurements of the domain structures is shown using piezoresponse force microscopy and X-ray diffraction, which confirms that these periodic structures are the same as those suggested in previous literature. © American Chemical Society.