%0 Journal Article %K lead %K thin films %K zirconium %K Domain walls %K Ferroelectric switching %K Ferroelastic domains %K Applied field %K Film orientations %K High field %K Kolmogorov %K Standard system %K Switching kinetics %A D Pantel %A Y.-H Chu %A L.W Martin %A Ramamoorthy Ramesh %A D Hesse %A M Alexe %B Journal of Applied Physics %D 2010 %G eng %R 10.1063/1.3392884 %T Switching kinetics in epitaxial BiFeO3 thin films %V 107 %X The switching kinetics in epitaxial (001)-, (110)-, and (111)-oriented BiFeO3 thin films were investigated as a function of applied field and time. It was found that the ferroelectric switching behavior obeys the Kolmogorov-Avrami-Ishibashi theory only in the high field range. The detailed behavior depends on the film orientation. A comparison with standard systems, such as epitaxial Pb (Zr0.2 Ti0.8) O3 films, reveals some similarities as well as some differences. For instance, the presence of 109° and 71° ferroelastic domain walls might be ruled out as the source of the decrease in switched polarization at low applied fields, in contrast to what is the case for a/c domain walls in tetragonal Pb (Zr 0.2 Ti0.8) O3. © 2010 American Institute of Physics.