%0 Journal Article %K Phase transitions %K Piezoelectricity %K Piezoelectric response %K Piezoelectric property %K Landau-Devonshire theory %K Misfit strains %K Mixed structure %K Orthorhombic phasis %K Single domains %A C.W Huang %A Y.H Chu %A Z.H Chen %A J Wang %A T Sritharan %A Q He %A Ramamoorthy Ramesh %A L Chen %B Applied Physics Letters %D 2010 %G eng %R 10.1063/1.3499658 %T Strain-driven phase transitions and associated dielectric/piezoelectric anomalies in BiFeO3 thin films %V 97 %X Strain-driven phase transitions and related intrinsic polarization, dielectric, and piezoelectric properties for single-domain films were studied for BiFeO3 using phenomenological Landau-Devonshire theory. A stable and mixed structure between tetragonal and rhombohedral-like (monoclinic) phases is predicted at a compressive misfit strain of um =-0.0382 without an energy barrier. For a tensile misfit strain of um =0.0272, another phase transition between the monoclinic and orthorhombic phases was predicted with sharply high dielectric and piezoelectric responses. © 2010 American Institute of Physics.