%0 Journal Article %K temperature %K microscopy %K electron %K chemistry %K electrons %K density functional theory %K Multiferroics %K Polarization %K Domain walls %K Article %K bismuth %K Electronic properties %K scanning tunneling microscopy %K Electronic configuration %K Cross-sectional scanning tunneling microscopies %K Electronic structure %K ferric ion %K Ferric Compounds %K Conducting channels %K Domain boundary %K Band gaps %K Scanning %K Atomic scale %K BiFeO3 %K Built-in potential %K Local electronic structures %K polarization discontinuity %K scanning tunneling microscopy (STM) %K Walls (structural partitions) %K Scanning Tunneling %A Y.-P Chiu %A Y.-T Chen %A B.-C Huang %A M.-C Shih %A J.-C Yang %A Q He %A C.-W Liang %A J Seidel %A Y.-C Chen %A Ramamoorthy Ramesh %A Y.-H Chu %B Advanced Materials %D 2011 %G eng %P 1530-1534 %R 10.1002/adma.201004143 %T Atomic-scale evolution of local electronic structure across multiferroic domain walls %V 23 %X Direct evidence of the electronic configurations across domain walls in BiFeO3 is quantitatively characterized by cross-sectional scanning tunneling microscopy. Atomic-scale band evolution and the asymmetrically built-in potential barrier at domain boundaries are demonstrated. The 109° domain walls register a remarkable decrease in the bandgap, suggesting a new route to control the local conducting channels within 2 nm. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.