%0 Journal Article %K nucleation %K transmission electron microscopy %K in-situ %K Electric fields %K Multiferroics %K Domain walls %K Ferroelectric materials %K polarization switching %K ferroelectricity %K Ferroelectric domains %K scanning transmission electron microscopy %K Multiferroic materials %K Ferroelectric films %K Ferroelastic domains %K Scanning probes %K Mesoscopics %K Bottom electrodes %K First-order %K In-Situ Study %K Local electric field %K Nucleation and growth %K Nucleation sites %K Phase-field modeling %K Scanning transmission electron microscopes %K Spatially resolved %K Conductive films %K Scanning %A H Chang %A S.V Kalinin %A S Yang %A P Yu %A S Bhattacharya %A P.P Wu %A N Balke %A S Jesse %A L.Q Chen %A Ramamoorthy Ramesh %A S.J Pennycook %A A.Y Borisevich %B Journal of Applied Physics %D 2011 %G eng %R 10.1063/1.3623779 %T Watching domains grow: In-situ studies of polarization switching by combined scanning probe and scanning transmission electron microscopy %V 110 %X Ferroelectric domain nucleation and growth in multiferroic BiFeO 3 films is observed directly by applying a local electric field with a conductive tip inside a scanning transmission electron microscope. The nucleation and growth of a ferroelastic domain and its interaction with pre-existing 71° domain walls are observed and compared with the results of phase-field modeling. In particular, a preferential nucleation site and direction-dependent pinning of domain walls are observed due to slow kinetics of metastable switching in the sample without a bottom electrode. These in situ spatially resolved observations of a first-order bias-induced phase transition reveal the mesoscopic mechanisms underpinning functionality of a wide range of multiferroic materials. © 2011 American Institute of Physics.