%0 Journal Article %K Multiferroics %K Nanotechnology %K Photovoltaic %K Ferroelectricity %K Electrostatic potentials %K Nanoscale %K Photovoltaic effects %K Scanning probes %K Domain boundary %K Conductive AFM %K Current voltage %K Domain structure %K Electrode spacing %K I-V measurements %K Mesoscopics %K Photovoltages %K Polarization direction %K Stripe domain %A J Seidel %A S.-Y Yang %A E Alarcón-Lladó %A Joel W Ager %A Ramamoorthy Ramesh %B Ferroelectrics %D 2012 %G eng %P 123-126 %R 10.1080/00150193.2012.678156 %T Nanoscale probing of high photovoltages at 109 domain walls %V 433 %X We report the direct observation of nanoscale photovoltaic current-voltage properties associated with directional steps of the electrostatic potential at 109 domain walls in ferroelectric BiFeO 3 thin films with highly ordered ferroelectric stripe domains. The unidirectional photovoltaic effect along the net-in-plane polarization direction is shown to exhibit anomalies at the micro-and nanoscale due to local differences in mesoscopic domain structure. Very high initial photovoltages for small electrode spacings are observed using a conductive AFM tip as one of the electrodes in photovoltaic I-V measurements. © 2012 Taylor & Francis Group, LLC.