%0 Journal Article %K Ferroelectric materials %K Boltzmann equation %K ferroelectricity %K negative capacitance %K Ferroelectric devices %K Ferroelectric capacitors %K Capacitance %K Ferroelectric films %K Energy dissipation %K Capacitors %K Boltzmann distribution %K Direct measurement %K Epitaxial ferroelectric films %K Fundamental barriers %K Intrinsic energy %K New applications %A A.I Khan %A K Chatterjee %A B Wang %A S Drapcho %A L You %A C Serrao %A S.R Bakaul %A Ramamoorthy Ramesh %A S Salahuddin %B Nature Materials %D 2015 %G eng %I Nature Publishing Group %P 182-186 %R 10.1038/nmat4148 %T Negative capacitance in a ferroelectric capacitor %V 14 %X The Boltzmann distribution of electrons poses a fundamental barrier to lowering energy dissipation in conventional electronics, often termed as Boltzmann Tyranny. Negative capacitance in ferroelectric materials, which stems from the stored energy of a phase transition, could provide a solution, but a direct measurement of negative capacitance has so far been elusive. Here, we report the observation of negative capacitance in a thin, epitaxial ferroelectric film. When a voltage pulse is applied, the voltage across the ferroelectric capacitor is found to be decreasing with time - in exactly the opposite direction to which voltage for a regular capacitor should change. Analysis of this inductance -like behaviour from a capacitor presents an unprecedented insight into the intrinsic energy profile of the ferroelectric material and could pave the way for completely new applications. © 2015 Macmillan Publishers Limited. All rights reserved.