%0 Journal Article %K cool roofs %K Pigment characterization %K Solar spectral optical properties %K Kubelka-Munk absorption and backscattering coefficients %K Titanium dioxide %A Ronnen M Levinson %A Paul H Berdahl %A Hashem Akbari %B Solar Energy Materials and Solar Cells %D 2005 %G eng %N 4 %P 351-389 %R 10.1016/j.solmat.2004.11.013 %T Solar spectral optical properties of pigments—Part II: survey of common colorants %V 89 %8 12/2005 %X

Various pigments are characterized by determination of parameters S (backscattering) and K (absorption) as functions of wavelength in the solar spectral range of 300–2500 nm. Measured values of S for generic titanium dioxide (rutile) white pigment are in rough agreement with values computed from the Mie theory, supplemented by a simple multiple scattering model. Pigments in widespread use are examined, with particular emphasis on those that may be useful for formulating non-white materials that can reflect the near-infrared (NIR) portion of sunlight, such as the complex inorganic color pigments (mixed metal oxides). These materials remain cooler in sunlight than comparable NIR-absorbing colors. NIR-absorptive pigments are to be avoided. High NIR reflectance can be produced by a reflective metal substrate, an NIR-reflective underlayer, and/or by the use of a pigment that scatters strongly in the NIR.