%0 Journal Article
%K Nickel
%K Zinc
%K Electrodes
%K Nickel oxide
%A Waltraud Taucher
%A Thomas C Adler
%A Frank R McLarnon
%A Elton J Cairns
%B Journal of Power Sources
%D 1996
%F Electrochem
%G eng
%N 1
%P 93-97
%R 10.1016/0378-7753(96)02327-0
%T Development of lightweight nickel electrodes for zinc/nickel oxide cells
%V 58
%8 01/1996
%X <p>A method for fabricating lightweight nickel electrodes has been developed by electrochemical impregnation of two different nickel fiber substrates. The electrochemical impregnation technique was applied galvanostatically at 35–50 mA/cm<sup>2</sup> in acidic solutions of nickel and cobalt nitrates (pH = 3). The nickel and cobalt contents of impregnated and formed electrodes was analyzed with atomic absorption spectrometry (AAS) and the amount of active nickel hydroxide was calculated. NiOOH electrode cycle-life performance testing was carried out in alkaline electrolyte (4.2–6.9 M KOH, 1 M LiOH) at a ∼<em>C</em>/5 rate during charge and discharge. Electrodes based on substrate materials of high porosity (90%, FN 090 Nickel Felt, Sorapec) deliver excellent specific capacities of 133–145 mAh/g in moderately alkaline electrolyte (4.2 M KOH) with an active material utilization of 67–95% depending on the quantity of co-precipitated cobalt (1.3–8.3%). NiOOH electrodes using substrates with lower porosity (81%, Fibrex 50/50 = fiber/Ni powder, National Standard) obtain very stable specific capacities (400 cycles) of 91–93 mAh/g with a utilization rate of 110% in highly alkaline electrolytes (6.9 M KOH).</p>