%0 Journal Article %K photocatalytic %K Hydrogen %K Ag2S/CdS %K Solar light %A Shaohua Shen %A Liejin Guo %A Xiaobo Chen %A Feng Ren %A Samuel S Mao %B International Journal of Hydrogen Energy %D 2010 %G eng %N 13 %P 7110-7115 %R 10.1016/j.ijhydene.2010.02.013 %T Effect of Ag2S on solar-driven photocatalytic hydrogen evolution of nanostructured CdS %V 35 %8 07/2010 %X

Nanostructured Ag2S/CdS were synthesized by a two-step precipitation method, and characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), and UV–Vis absorption spectra. With Ag2S highly dispersed in the CdS nanostructures, the photoactivity was evaluated by hydrogen evolution from aqueous solution containing Na2S/Na2SO3 as a hole scavenger under simulated solar light (AM1.5). When the concentration of Ag2S was 5% by weight, Ag2S/CdS showed the highest photocatalytic activity for hydrogen evolution, with the solar-hydrogen energy conversion efficiency approximately 0.7%. We investigated the effect of highly dispersed Ag2S on the photoactivity.