%0 Journal Article %K Model %K Condensation %K Particle %K Particles %K Copper %K Ablation %K Laser %K Laser ablation %K Laser ablation %K Analysis %K X-Ray %K Composition %K Liquid %K Brass %K Vapor %K Zinc %K Droplet %K Droplets %K Size %K Diameter %K Particle-size %K Layer %K Chemistry %A Chunyi Liu %A Xianglei Mao %A Samuel S Mao %A Ralph Greif %A Richard E Russo %B Analytical Chemistry %D 2005 %F Laser %G eng %N 20 %P 6687-6691 %R 10.1021/ac0508696 %T Particle-size dependent chemistry from laser ablation of brass %V 77 %8 10/2005 %! Anal. Chem. %X

The proportion of zinc and copper in particles formed by laser ablation of brass was found to vary with the particle diameter. Energy-dispersive X-ray analysis showed that smaller particles were zinc enhanced while larger particles were composed mostly of copper. A model based on condensation of vapor onto large droplets ejected from a melted liquid layer is proposed to describe the change in particle composition versus size.