%0 Journal Article %K lithium %K lithium compounds %K manganese compounds %K polymers %K secondary cells %A Guoying Chen %A Thomas J Richardson %B Journal of Electrochemical Society %D 2010 %G eng %N 6 %P A735-A740 %R 10.1149/1.3392370 %T Overcharge Protection for 4 V Lithium Batteries at High Rates and Low Temperatures %V 157 %X

Overcharge protection for 4 V Li1.05Mn1.95O4/lithium cells at charging rates in excess of 1 mA/cm2 (3C) and at temperatures of as low as −20°C was achieved using a bilayer separator coated with two electroactive polymers. High rate and low temperature overcharge protection and discharge performance were improved by employing a design in which the polymer-coated portion of the separator is in parallel with the cell rather than between the electrodes. The effects of different membrane supports for the electroactive polymers were also examined.