%0 Journal Article %A Wanqing Cao %A Arlon J Hunt %B Solid State Communications %D 1994 %G eng %P 645-648 %T Thermal annealing of photoluminescent Si deposited on silica aerogels %V 91 %X

Photoluminescence (PL) of chemically vapor deposited Si on silica aerogels has been investigated as a function of annealing temperature up to 650°C in air. The PL peak red shifts considerably with temperatures up to 350°C and then slightly blue shifts above 350°C. There are at least two different oxidation stages in the thermal annealing of porous Si: surface oxidation below 350°C, which results in higher luminescence yield particularly for large Si particles, and internal oxidation above 350°C, which reduces the effective particle size.