%0 Journal Article %A Monica Veszelei %A Lisen Kullman %A Claes G Granqvist %A Klaus von Rottkay %A Michael D Rubin %B Applied Optics %D 1998 %G eng %N 25 %P 5993-6001 %R 10.1364/AO.37.005993 %T Optical Constants of Sputter-Deposited Ti-Ce Oxide and Zr-Ce Oxide Films %V 37 %1
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%2 LBNL-42059 %8 09/1998 %XFilms of Ti oxide, Zr oxide, Ce oxide, Ti-Ce oxide, and Zr-Ce oxide were made by means of reactive dc magnetron sputtering in a multitarget arrangement. The films were characterized by x-ray diffraction and electrochemical measurements, both techniques being firmly connected to stoichiometric information. The optical constants n and k were evalued from spectrophotometry and from variable-angle spectroscopic ellipsometry. The two analyses gave consistent results. It was found that n for the mixed-oxide films varied smoothly between the values for the pure oxides, whereas k in the band-gap range showed characteristic differences between Ti-Ce oxide and Zr-Ce oxide. It is speculated that this difference is associated with structural effects.