Materials are more easily damaged during accidents that involve rapid deformation. Here, a design strategy is described for electronic materials comprised of conducting polymers that defies this orthodox property, making their extensibility and toughness dynamically adaptive to deformation rates. This counterintuitive property is achieved through a morphology of interconnected nanoscopic core–shell micelles, where the chemical interactions are stronger within the shells than the cores. As a result, the interlinked shells retain material integrity under strain, while the rate of dissociation of the cores controls the extent of micelle elongation, which is a process that adapts to deformation rates. A prototype based on polyaniline shows a 7.5-fold increase in ultimate elongation and a 163-fold increase in toughness when deformed at increasing rates from 2.5 to 10 000% min−1. This concept can be generalized to other conducting polymers and highly conductive composites to create “self-protective” soft electronic materials with enhanced durability under dynamic movement or deformation.
BT - Small DA - 08/2023 DO - https://doi.org/10.1002/smll.202207100 IS - 35 LA - eng N2 -Materials are more easily damaged during accidents that involve rapid deformation. Here, a design strategy is described for electronic materials comprised of conducting polymers that defies this orthodox property, making their extensibility and toughness dynamically adaptive to deformation rates. This counterintuitive property is achieved through a morphology of interconnected nanoscopic core–shell micelles, where the chemical interactions are stronger within the shells than the cores. As a result, the interlinked shells retain material integrity under strain, while the rate of dissociation of the cores controls the extent of micelle elongation, which is a process that adapts to deformation rates. A prototype based on polyaniline shows a 7.5-fold increase in ultimate elongation and a 163-fold increase in toughness when deformed at increasing rates from 2.5 to 10 000% min−1. This concept can be generalized to other conducting polymers and highly conductive composites to create “self-protective” soft electronic materials with enhanced durability under dynamic movement or deformation.
PY - 2023 ST - Small T2 - Small TI - Deformation Rate‐Adaptive Conducting Polymers and Composites UR - https://onlinelibrary.wiley.com/toc/16136829/19/35 VL - 19 SN - 1613-6810 ER -