TY - JOUR KW - Optimization KW - Microstructure KW - Thin films KW - Sputter deposition KW - Electrodes KW - Hysteresis KW - Lanthanum compounds KW - Doping (additives) KW - Lead compounds KW - Capacitors KW - Lead zirconate titanate (PZT) KW - Fatigue of materials KW - Imprint behavior KW - Fatigue performance KW - High density nonvolatile memory (HDNVM) KW - Hysteresis loop characteristics KW - Oxide electrode technology AU - B.A Tuttle AU - H.N Al-Shareef AU - W.L Warren AU - M.V Raymond AU - T.J Headley AU - J.A Voigt AU - J Evans AU - Ramamoorthy Ramesh AB - Oxide electrode technology is investigated for optimization of Pb(Zr,Ti)O3 (PZT) thin film capacitor properties for high density nonvolatile memory applications. PZT thin film capacitors with RF sputter deposited La0.5Sr0.5CoO3 (LSCO) electrodes have been characterized with respect to the following parameters: initial dielectric hysteresis loop characteristics, fatigue performance, microstructure and imprint behavior. Our studies have determined that the fatigue of PZT capacitors with LSCO electrodes is less sensitive to B site cation ratio and underlying electrode stack technology than with RuO2 electrodes. Doping PZT thin films with Nb (PNZT) improves imprint behavior of LSCO//PZT//LSCO capacitors considerably. We have demonstrated that PNZT 4/30/70 // LSCO capacitors thermally processed at either 550°C or 675°C have almost identical initial hysteresis properties and exhibit essentially no fatigue out to approximately 1010 cycles. © 1995. BT - Microelectronic Engineering DO - 10.1016/0167-9317(95)00150-6 LA - eng M1 - 1-4 N1 - cited By 12 N2 - Oxide electrode technology is investigated for optimization of Pb(Zr,Ti)O3 (PZT) thin film capacitor properties for high density nonvolatile memory applications. PZT thin film capacitors with RF sputter deposited La0.5Sr0.5CoO3 (LSCO) electrodes have been characterized with respect to the following parameters: initial dielectric hysteresis loop characteristics, fatigue performance, microstructure and imprint behavior. Our studies have determined that the fatigue of PZT capacitors with LSCO electrodes is less sensitive to B site cation ratio and underlying electrode stack technology than with RuO2 electrodes. Doping PZT thin films with Nb (PNZT) improves imprint behavior of LSCO//PZT//LSCO capacitors considerably. We have demonstrated that PNZT 4/30/70 // LSCO capacitors thermally processed at either 550°C or 675°C have almost identical initial hysteresis properties and exhibit essentially no fatigue out to approximately 1010 cycles. © 1995. PY - 1995 SP - 223 EP - 230 T2 - Microelectronic Engineering TI - La0.5Sr0.5CoO3 electrode technology for Pb(Zr,Ti)O3 thin film nonvolatile memories VL - 29 SN - 01679317 ER -