TY - CPAPER KW - Cooling KW - Pulsed laser deposition KW - Crystal orientation KW - Electrodes KW - Hysteresis KW - Lanthanum compounds KW - Polarization KW - Ferroelectric materials KW - Heterojunctions KW - Lead compounds KW - Capacitors KW - Pulsed laser applications KW - Lanthanum strontium cobalt oxide KW - Fatigue of materials KW - Titanium oxides KW - Imprint behavior KW - Lead lanthanum zirconium titanate KW - Oxygen ambient AU - J Lee AU - Ramamoorthy Ramesh AU - V.G Keramidas AB - La-Sr-Co-O(LSCO)/Pb-La-Zr-Ti-O(PLZT)/La-Sr-Co-O heterostructures with different crystalline quality have been grown on LaAlO3 and Si with a bismuth titanate template layer. Imprint of the heterostructures are investigated in comparison with fatigue and retention. Oxygen ambient during cooling the heterostructures was also varied to investigate the imprint. With consideration of the switching behavior caused by imprint, imprint behavior was deconvoluted from fatigue and retention. In epitaxial PLZT capacitors grown on LaAlO3, imprint behavior was found to be significantly dependent on the oxygen ambient. As the oxygen ambient became more reducing, the capacitors developed more voltage asymmetry in hysteresis loops and a more preferred polarization state directed towards the top electrode. On the other hand, oriented PLZT capacitors exhibited less pronounced effect of the oxygen ambient on the imprint behavior. BT - Proceedings of the Materials Research Society Symposium - LA - eng N1 - cited By 12 N2 - La-Sr-Co-O(LSCO)/Pb-La-Zr-Ti-O(PLZT)/La-Sr-Co-O heterostructures with different crystalline quality have been grown on LaAlO3 and Si with a bismuth titanate template layer. Imprint of the heterostructures are investigated in comparison with fatigue and retention. Oxygen ambient during cooling the heterostructures was also varied to investigate the imprint. With consideration of the switching behavior caused by imprint, imprint behavior was deconvoluted from fatigue and retention. In epitaxial PLZT capacitors grown on LaAlO3, imprint behavior was found to be significantly dependent on the oxygen ambient. As the oxygen ambient became more reducing, the capacitors developed more voltage asymmetry in hysteresis loops and a more preferred polarization state directed towards the top electrode. On the other hand, oriented PLZT capacitors exhibited less pronounced effect of the oxygen ambient on the imprint behavior. PB - Materials Research Society, Pittsburgh, PA, United States PY - 1995 SP - 67 EP - 78 T2 - Proceedings of the Materials Research Society Symposium - T3 - Materials Research Society Symposium - TI - Imprint of La-Sr-Co-O/Pb-La-Zr-Ti-O/La-Sr-Co-O heterostructures grown by pulsed laser deposition VL - 361 SN - 02729172 ER -