TY - JOUR AU - V Nagarajan AU - C.S Ganpule AU - H Li AU - L Salamanca-Riba AU - A.L Roytburd AU - E.D Williams AU - Ramamoorthy Ramesh AB - We have investigated the polydomain formation in 100-200-nm-thick PbZr0.2Ti0.8O3 epitaxial thin films on vicinally cut (100) oriented SrTiO3 substrates. Our results show that there is a preferential location of the nucleation of the a domains along the step edges of the underlying substrate. By piezo-response microscopy, we show that all a domains have their polarization aligned along the same direction. This result is in contrast to flat substrates where fourfold symmetry of a domains is observed. We observe that the critical thickness for a domain formation is much lower than that for PbZr0.2Ti0.8O3 films grown on flat substrates. We have developed a model based on minimization of elastic energy to describe the effect of localized stresses at step edges on the formation of a domains in the ferroelectric layer. © 2001 American Institute of Physics. BT - Applied Physics Letters DO - 10.1063/1.1402645 LA - eng M1 - 17 N1 - cited By 25 N2 - We have investigated the polydomain formation in 100-200-nm-thick PbZr0.2Ti0.8O3 epitaxial thin films on vicinally cut (100) oriented SrTiO3 substrates. Our results show that there is a preferential location of the nucleation of the a domains along the step edges of the underlying substrate. By piezo-response microscopy, we show that all a domains have their polarization aligned along the same direction. This result is in contrast to flat substrates where fourfold symmetry of a domains is observed. We observe that the critical thickness for a domain formation is much lower than that for PbZr0.2Ti0.8O3 films grown on flat substrates. We have developed a model based on minimization of elastic energy to describe the effect of localized stresses at step edges on the formation of a domains in the ferroelectric layer. © 2001 American Institute of Physics. PY - 2001 SP - 2805 EP - 2807 T2 - Applied Physics Letters TI - Control of domain structure of epitaxial PbZr0.2Ti0.8O3 thin films grown on vicinal (001) SrTiO3 substrates VL - 79 SN - 00036951 ER -