TY - JOUR KW - Oxidation KW - Thin films KW - Copper KW - Diffusion KW - Annealing KW - Electrodes KW - Materials science KW - Permittivity KW - Capacitors KW - Synthesis (chemical) KW - Barium compounds KW - Leakage currents KW - Dielectric losses KW - Diffusion barrier AU - W Fan AU - B Kabius AU - J.M Miller AU - S Saha AU - J.A Carlisle AU - O Auciello AU - R.P.H Chang AU - Ramamoorthy Ramesh AB - An investigation on the synthesis and material properties of layered TiAl/Cu/Ta electrodes was performed to achieve the integration of Cu electrodes. The TiAl layer provided an excellent barrier against oxygen diffusion into the Cu layer to inhibit Cu oxidation while the Ta layer is an excellent diffusion barrier to inhibit deleterious Cu diffusion into the Si substrate. Using the surface analytical methods, characterization of the Cu-based layered structure showed that two amorphous oxide layers were formed on both sides of the TiAl barrier. BT - Journal of Applied Physics DO - 10.1063/1.1616984 LA - eng M1 - 9 N1 - cited By 32 N2 - An investigation on the synthesis and material properties of layered TiAl/Cu/Ta electrodes was performed to achieve the integration of Cu electrodes. The TiAl layer provided an excellent barrier against oxygen diffusion into the Cu layer to inhibit Cu oxidation while the Ta layer is an excellent diffusion barrier to inhibit deleterious Cu diffusion into the Si substrate. Using the surface analytical methods, characterization of the Cu-based layered structure showed that two amorphous oxide layers were formed on both sides of the TiAl barrier. PY - 2003 SP - 6192 EP - 6200 T2 - Journal of Applied Physics TI - Materials science and integration bases for fabrication of (Ba xSr1-x)TiO3 thin film capacitors with layered Cu-based electrodes VL - 94 SN - 00218979 ER -