TY - JOUR KW - Evaluation KW - Electricity KW - Decomposition KW - Temperature KW - Pulsed laser deposition KW - Transmission electron microscopy KW - Methodology KW - Anisotropy KW - Perovskite KW - Iron KW - Semiconductor KW - Chemistry KW - Semiconductors KW - Nanostructured materials KW - Crystallization KW - Crystallography KW - Iron compounds KW - Lanthanum compounds KW - Materials KW - Materials testing KW - Nanotechnology KW - Article KW - Single crystals KW - Ferromagnetic materials KW - Magnetization KW - Surface properties KW - Ferric oxide KW - Thermodynamics KW - Surface property KW - Ferric ion KW - Ferric Compounds KW - Conformation KW - Ultrastructure KW - Molecular Conformation KW - Self-assembly KW - Energy dispersive spectroscopy KW - Iron nanowires KW - Self-assembled nanowires KW - Specific energy KW - Thermodynamic equilibrium KW - Nanotube KW - Metallurgy KW - Electric Wiring KW - Manufactured Materials KW - Nanotubes AU - L Mohaddes-Ardabili AU - H Zheng AU - S.B Ogale AU - B Hannoyer AU - W Tian AU - J Wang AU - S.E Lofland AU - S.R Shinde AU - T Zhao AU - Y Jia AU - L Salamanca-Riba AU - D.G Schlom AU - M Wuttig AU - Ramamoorthy Ramesh AB - Arrays of perpendicular ferromagnetic nanowires have recently attracted considerable interest for their potential use in many areas of advanced nanotechnology. We report a simple approach to create self-assembled nanowires of α-Fe through the decomposition of a suitably chosen perovskite. We illustrate the principle behind this approach using the reaction 2La 0.5Sr0.5FeO3 → LaSrFeO4 + Fe + O2 that occurs during the deposition of La0.5Sr 0.5FeO3 under reducing conditions. This leads to the spontaneous formation of an array of single-crystalline α-Fe nanowires embedded in LaSrFeO4 matrix, which grow perpendicular to the substrate and span the entire film thickness. The diameter and spacing of the nanowires are controlled directly by deposition temperature. The nanowires show uniaxial anisotropy normal to the film plane and magnetization close to that of bulk α-Fe. The high magnetization and sizable coercivity of the nanowires make them desirable for high-density data storage and other magnetic-device applications. BT - Nature Materials DO - 10.1038/nmat1162 LA - eng M1 - 8 N1 - cited By 123 N2 - Arrays of perpendicular ferromagnetic nanowires have recently attracted considerable interest for their potential use in many areas of advanced nanotechnology. We report a simple approach to create self-assembled nanowires of α-Fe through the decomposition of a suitably chosen perovskite. We illustrate the principle behind this approach using the reaction 2La 0.5Sr0.5FeO3 → LaSrFeO4 + Fe + O2 that occurs during the deposition of La0.5Sr 0.5FeO3 under reducing conditions. This leads to the spontaneous formation of an array of single-crystalline α-Fe nanowires embedded in LaSrFeO4 matrix, which grow perpendicular to the substrate and span the entire film thickness. The diameter and spacing of the nanowires are controlled directly by deposition temperature. The nanowires show uniaxial anisotropy normal to the film plane and magnetization close to that of bulk α-Fe. The high magnetization and sizable coercivity of the nanowires make them desirable for high-density data storage and other magnetic-device applications. PB - Nature Publishing Group PY - 2004 SP - 533 EP - 538 T2 - Nature Materials TI - Self-assembled single-crystal ferromagnetic iron nanowires formed by decomposition VL - 3 SN - 14761122 ER -