TY - JOUR KW - Cooling KW - Perovskite KW - Nanostructured materials KW - Integration KW - Polarization KW - Ferroelectric materials KW - Boundary conditions KW - Dielectric properties KW - Thermodynamics KW - Thermal effects KW - Barium compounds KW - Ultrathin films KW - Vectors KW - Dielectric stiffness KW - Nanometers KW - Stress fields KW - Threading dislocation density KW - Stiffness AU - S.P Alpay AU - I.B Misirlioglu AU - V Nagarajan AU - Ramamoorthy Ramesh AB - The role of dislocations in ferroelectric materials was investigated by a thermodynamic analysis. A drastic variation in the polarization near the dislocation is observed due to the coupling of the stress field of the dislocation and polarization. These polarization gradients result in string depolarizing fields that suppress the polarization in a region that extends over several nanometers. The deterimental effect of such regions increases in ultrathin ferroelectric thin films and play a crucial extrinsic role in size effect studies of ferroelectrics. BT - Applied Physics Letters DO - 10.1063/1.1788894 LA - eng M1 - 11 N1 - cited By 137 N2 - The role of dislocations in ferroelectric materials was investigated by a thermodynamic analysis. A drastic variation in the polarization near the dislocation is observed due to the coupling of the stress field of the dislocation and polarization. These polarization gradients result in string depolarizing fields that suppress the polarization in a region that extends over several nanometers. The deterimental effect of such regions increases in ultrathin ferroelectric thin films and play a crucial extrinsic role in size effect studies of ferroelectrics. PY - 2004 SP - 2044 EP - 2046 T2 - Applied Physics Letters TI - Can interface dislocations degrade ferroelectric properties? VL - 85 SN - 00036951 ER -