TY - JOUR KW - Thin films KW - Bismuth compounds KW - Charge transfer KW - Cooling pressure KW - Dark conductivities KW - Photoconductivity KW - Thermal effects AU - S.R Basu AU - L.W Martin AU - Y.H Chu AU - M Gajek AU - Ramamoorthy Ramesh AU - R.C Rai AU - X Xu AU - J.L Musfeldt AB - The optical properties of epitaxial BiFe O3 thin films have been characterized in the visible range. Variable temperature spectra show an absorption onset near 2.17 eV, a direct gap (2.667±0.005 eV at 300 K), and charge transfer excitations at higher energy. Additionally, we report photoconductivity in BiFe O3 films under illumination from a 100 mW cm2 white light source. A direct correlation is observed between the magnitude of the photoconductivity and postgrowth cooling pressure. Dark conductivities increased by an order of magnitude when comparing films cooled in 760 and 0.1 Torr. Large increases in photoconductivity are observed in light. © 2008 American Institute of Physics. BT - Applied Physics Letters DO - 10.1063/1.2887908 LA - eng M1 - 9 N1 - cited By 370 N2 - The optical properties of epitaxial BiFe O3 thin films have been characterized in the visible range. Variable temperature spectra show an absorption onset near 2.17 eV, a direct gap (2.667±0.005 eV at 300 K), and charge transfer excitations at higher energy. Additionally, we report photoconductivity in BiFe O3 films under illumination from a 100 mW cm2 white light source. A direct correlation is observed between the magnitude of the photoconductivity and postgrowth cooling pressure. Dark conductivities increased by an order of magnitude when comparing films cooled in 760 and 0.1 Torr. Large increases in photoconductivity are observed in light. © 2008 American Institute of Physics. PY - 2008 T2 - Applied Physics Letters TI - Photoconductivity in BiFeO3 thin films VL - 92 SN - 00036951 ER -