TY - JOUR KW - Wavelength KW - Nonlinear optical properties (NLO) KW - Spectroscopic ellipsometry KW - Harmonic generation KW - Bismuth compounds KW - Antiferromagnetic materials KW - Refractive index KW - Nonlinear optical coefficients AU - A Kumar AU - R.C Rai AU - N.J Podraza AU - S Denev AU - M Ramirez AU - Y.-H Chu AU - L.W Martin AU - J Ihlefeld AU - T Heeg AU - J Schubert AU - D.G Schlom AU - J Orenstein AU - Ramamoorthy Ramesh AU - R.W Collins AU - J.L Musfeldt AU - V Gopalan AB - Using spectroscopic ellipsometry, the room temperature refractive index and absorption versus wavelength of the ferroelectric antiferromagnet bismuth ferrite, BiFe O3, are reported. The material has a direct band gap at 442 nm wavelength (2.81 eV). Using optical second harmonic generation, the nonlinear optical coefficients were determined to be d15 d22 =0.20±0.01, d31 d22 =0.35±0.02, d33 d22 =-11.4±0.20, and ∫ d22 ∫ =298.4±6.1 pmV at a fundamental wavelength of 800 nm. © 2008 American Institute of Physics. BT - Applied Physics Letters DO - 10.1063/1.2901168 LA - eng M1 - 12 N1 - cited By 185 N2 - Using spectroscopic ellipsometry, the room temperature refractive index and absorption versus wavelength of the ferroelectric antiferromagnet bismuth ferrite, BiFe O3, are reported. The material has a direct band gap at 442 nm wavelength (2.81 eV). Using optical second harmonic generation, the nonlinear optical coefficients were determined to be d15 d22 =0.20±0.01, d31 d22 =0.35±0.02, d33 d22 =-11.4±0.20, and ∫ d22 ∫ =298.4±6.1 pmV at a fundamental wavelength of 800 nm. © 2008 American Institute of Physics. PY - 2008 T2 - Applied Physics Letters TI - Linear and nonlinear optical properties of BiFeO3 VL - 92 SN - 00036951 ER -