TY - JOUR KW - Thin films KW - Molecular beam epitaxy KW - Substrates KW - Spectroscopic ellipsometry KW - Bismuth compounds KW - Energy gap KW - Four-circle x-ray diffraction KW - Multiple-angle spectroscopic ellipsometry KW - Optical band gap KW - Oxygen activity AU - J.F Ihlefeld AU - N.J Podraza AU - Z.K Liu AU - R.C Rai AU - X Xu AU - T Heeg AU - Y.B Chen AU - J Li AU - R.W Collins AU - J.L Musfeldt AU - X.Q Pan AU - J Schubert AU - Ramamoorthy Ramesh AU - D.G Schlom AB - BiFe O3 thin films have been deposited on (001) SrTi O3 substrates by adsorption-controlled reactive molecular-beam epitaxy. For a given bismuth overpressure and oxygen activity, single-phase BiFe O3 films can be grown over a range of deposition temperatures in accordance with thermodynamic calculations. Four-circle x-ray diffraction reveals phase-pure, epitaxial films with ω rocking curve full width at half maximum values as narrow as 29 arc sec (0.008°). Multiple-angle spectroscopic ellipsometry reveals a direct optical band gap at 2.74 eV for stoichiometric as well as 5% bismuth-deficient single-phase BiFe O3 films. © 2008 American Institute of Physics. BT - Applied Physics Letters DO - 10.1063/1.2901160 LA - eng M1 - 14 N1 - cited By 256 N2 - BiFe O3 thin films have been deposited on (001) SrTi O3 substrates by adsorption-controlled reactive molecular-beam epitaxy. For a given bismuth overpressure and oxygen activity, single-phase BiFe O3 films can be grown over a range of deposition temperatures in accordance with thermodynamic calculations. Four-circle x-ray diffraction reveals phase-pure, epitaxial films with ω rocking curve full width at half maximum values as narrow as 29 arc sec (0.008°). Multiple-angle spectroscopic ellipsometry reveals a direct optical band gap at 2.74 eV for stoichiometric as well as 5% bismuth-deficient single-phase BiFe O3 films. © 2008 American Institute of Physics. PY - 2008 T2 - Applied Physics Letters TI - Optical band gap of BiFe O3 grown by molecular-beam epitaxy VL - 92 SN - 00036951 ER -