TY - JOUR KW - Thin films KW - Polarization KW - Rotation KW - Spontaneous polarizations KW - Epitaxial films KW - Induced polarization KW - Thick films KW - Thermoanalysis AU - H.W Jang AU - S.H Baek AU - D Ortiz AU - C.M Folkman AU - R.R Das AU - Y.H Chu AU - P Shafer AU - J.X Zhang AU - S Choudhury AU - V Vaithyanathan AU - Y.B Chen AU - D.A Felker AU - M.D Biegalski AU - M.S Rzchowski AU - X.Q Pan AU - D.G Schlom AU - L.Q Chen AU - Ramamoorthy Ramesh AU - C.B Eom AB - Direct measurement of the remanent polarization of high quality (001)-oriented epitaxial BiFeO3 thin films shows a strong strain dependence, even larger than conventional (001)-oriented PbTiO3 films. Thermodynamic analysis reveals that a strain-induced polarization rotation mechanism is responsible for the large change in the out-of-plane polarization of (001) BiFeO3 with biaxial strain while the spontaneous polarization itself remains almost constant. © 2008 The American Physical Society. BT - Physical Review Letters DO - 10.1103/PhysRevLett.101.107602 LA - eng M1 - 10 N1 - cited By 186 N2 - Direct measurement of the remanent polarization of high quality (001)-oriented epitaxial BiFeO3 thin films shows a strong strain dependence, even larger than conventional (001)-oriented PbTiO3 films. Thermodynamic analysis reveals that a strain-induced polarization rotation mechanism is responsible for the large change in the out-of-plane polarization of (001) BiFeO3 with biaxial strain while the spontaneous polarization itself remains almost constant. © 2008 The American Physical Society. PY - 2008 T2 - Physical Review Letters TI - Strain-induced polarization rotation in epitaxial (001) BiFeO3 thin films VL - 101 SN - 00319007 ER -