TY - JOUR KW - Substrates KW - Ferroelectricity KW - Single crystals KW - Ferroelectric films KW - Ferroelectric switching KW - Ferroelastic domains KW - Bottom electrodes KW - Epitaxial films KW - Unit cells KW - Semiconducting bismuth compounds KW - X-ray diffractions KW - Growth (materials) KW - Semiconducting silicon compounds KW - X-ray diffraction analysis KW - Atomic-force microscopies KW - Device applications KW - Domain engineerings KW - Ferroelectric properties KW - High qualities KW - High resolutions KW - HRXRD KW - Reciprocal space mappings KW - Si substrates KW - Step-flow growths KW - Stripe domains KW - Substrate anisotropies KW - Variant selections AU - H.W Jang AU - D Ortiz AU - S.-H Baek AU - C.M Folkman AU - R.R Das AU - P Shafer AU - Yimin Chen AU - C.T Nelson AU - X Pan AU - Ramamoorthy Ramesh AU - C.-B Eom AB - The ferroelastic domain variant selection in (001) BiFeO3 films on miscut (001) SrTiO3 substrates with coherent SrRuO3 bottom electrodes and its effect on the ferroelectric properties of the films were reported. This study showed an improvement in the ferroelectric switching behavior and leakage current in BiFeO3 films applying domain engineering. Atomic force microscopy (AFM), reciprocal space mapping (RSM), and high-resolution X-ray diffraction (HRXRD) used in the study showed that miscut substrate directed the step-flow growth and two-variant stripe domains in the BiFeO3 films. The preferential distortion of unit cells and the complete step-flow growth induced by the substrate anisotropy created two-variant stripe domains in (001) BiFeO3 films. Domain engineering can be used for growing high-quality BiFeO3 films on cubic (001) Si substrates for device applications. BT - Advanced Materials DO - 10.1002/adma.200800823 LA - eng M1 - 7 N1 - cited By 224 N2 - The ferroelastic domain variant selection in (001) BiFeO3 films on miscut (001) SrTiO3 substrates with coherent SrRuO3 bottom electrodes and its effect on the ferroelectric properties of the films were reported. This study showed an improvement in the ferroelectric switching behavior and leakage current in BiFeO3 films applying domain engineering. Atomic force microscopy (AFM), reciprocal space mapping (RSM), and high-resolution X-ray diffraction (HRXRD) used in the study showed that miscut substrate directed the step-flow growth and two-variant stripe domains in the BiFeO3 films. The preferential distortion of unit cells and the complete step-flow growth induced by the substrate anisotropy created two-variant stripe domains in (001) BiFeO3 films. Domain engineering can be used for growing high-quality BiFeO3 films on cubic (001) Si substrates for device applications. PY - 2009 SP - 817 EP - 823 T2 - Advanced Materials TI - Domain engineering for enhanced ferroelectric properties of epitaxial (001) BiFeO thin films VL - 21 SN - 09359648 ER -