TY - JOUR KW - Stoichiometry KW - Spatial distribution KW - Electronic states KW - Electronic structure KW - Band gaps KW - Growth conditions KW - Semiconducting bismuth compounds KW - Cathodoluminescence spectroscopy KW - Defect emission KW - Defect state KW - Depth-resolved KW - Film properties KW - Interface electronics KW - Localized electronic state KW - Near-band edge emissions AU - J Zhang AU - M Rutkowski AU - L.W Martin AU - T Conry AU - Ramamoorthy Ramesh AU - J.F Ihlefeld AU - A Melville AU - D.G Schlom AU - L.J Brillson AB - The authors report on the depth-resolved cathodoluminescence spectroscopy studies of the surface, bulk, and interface-localized electronic states in the band gap of epitaxial BiFeO3 thin films. The BiFeO3 films show a near band edge emission at 2.7 eV and defect emissions at energies varying from 2.0 to 2.5 eV. The overall results clearly suggest that the electronic structure, especially the defect states and their spatial distributions, of BiFeO3 films are strongly dependent on the growth conditions and method, stoichiometry, and strain, so that understanding and controlling them are crucial to optimize BiFeO3 film properties. © 2009 American Vacuum Society. BT - Journal of Vacuum Science and Technology B: Microelectronics and Nanometer Structures DO - 10.1116/1.3130152 LA - eng M1 - 4 N1 - cited By 15 N2 - The authors report on the depth-resolved cathodoluminescence spectroscopy studies of the surface, bulk, and interface-localized electronic states in the band gap of epitaxial BiFeO3 thin films. The BiFeO3 films show a near band edge emission at 2.7 eV and defect emissions at energies varying from 2.0 to 2.5 eV. The overall results clearly suggest that the electronic structure, especially the defect states and their spatial distributions, of BiFeO3 films are strongly dependent on the growth conditions and method, stoichiometry, and strain, so that understanding and controlling them are crucial to optimize BiFeO3 film properties. © 2009 American Vacuum Society. PY - 2009 SP - 2012 EP - 2014 T2 - Journal of Vacuum Science and Technology B: Microelectronics and Nanometer Structures TI - Surface, bulk, and interface electronic states of epitaxial BiFeO 3 films VL - 27 SN - 10711023 ER -