TY - JOUR KW - Electric potential KW - Indium KW - Tin KW - Ferroelectricity KW - Ferroelectric polarization KW - Oxide heterostructures KW - Photovoltaic effects KW - Semiconducting bismuth compounds KW - Band offsets KW - External quantum efficiency KW - Maximum Efficiency KW - Open-circuit voltages KW - Order of magnitude KW - Tin doped indium oxide KW - Semiconducting indium compounds AU - S.Y Yang AU - L.W Martin AU - S.J Byrnes AU - T.E Conry AU - S.R Basu AU - D Paran AU - L Reichertz AU - J Ihlefeld AU - C Adamo AU - A Melville AU - Y.-H Chu AU - C.-H Yang AU - J.L Musfeldt AU - D.G Schlom AU - Joel W Ager AU - Ramamoorthy Ramesh AB - We report a photovoltaic effect in ferroelectric BiFeO3 thin films. The all-oxide heterostructures with SrRuO3 bottom and tin doped indium oxide top electrodes are characterized by open-circuit voltages ∼0.8-0.9 V and external quantum efficiencies up to ∼10% when illuminated with the appropriate light. Efficiencies are at least an order of magnitude larger than the maximum efficiency under sunlight (AM 1.5) thus far reported for ferroelectric-based devices. The dependence of the measured open-circuit voltage on film thickness suggests contributions to the large open-circuit voltage from both the ferroelectric polarization and band offsets at the BiFeO3 /tin doped indium oxide interface. © 2009 American Institute of Physics. BT - Applied Physics Letters DO - 10.1063/1.3204695 LA - eng M1 - 6 N1 - cited By 404 N2 - We report a photovoltaic effect in ferroelectric BiFeO3 thin films. The all-oxide heterostructures with SrRuO3 bottom and tin doped indium oxide top electrodes are characterized by open-circuit voltages ∼0.8-0.9 V and external quantum efficiencies up to ∼10% when illuminated with the appropriate light. Efficiencies are at least an order of magnitude larger than the maximum efficiency under sunlight (AM 1.5) thus far reported for ferroelectric-based devices. The dependence of the measured open-circuit voltage on film thickness suggests contributions to the large open-circuit voltage from both the ferroelectric polarization and band offsets at the BiFeO3 /tin doped indium oxide interface. © 2009 American Institute of Physics. PY - 2009 T2 - Applied Physics Letters TI - Photovoltaic effects in BiFeO3 VL - 95 SN - 00036951 ER -