TY - JOUR KW - Lead KW - Thin films KW - Zirconium KW - Domain walls KW - Ferroelectric switching KW - Ferroelastic domains KW - Applied field KW - Film orientations KW - High field KW - Kolmogorov KW - Standard system KW - Switching kinetics AU - D Pantel AU - Y.-H Chu AU - L.W Martin AU - Ramamoorthy Ramesh AU - D Hesse AU - M Alexe AB - The switching kinetics in epitaxial (001)-, (110)-, and (111)-oriented BiFeO3 thin films were investigated as a function of applied field and time. It was found that the ferroelectric switching behavior obeys the Kolmogorov-Avrami-Ishibashi theory only in the high field range. The detailed behavior depends on the film orientation. A comparison with standard systems, such as epitaxial Pb (Zr0.2 Ti0.8) O3 films, reveals some similarities as well as some differences. For instance, the presence of 109° and 71° ferroelastic domain walls might be ruled out as the source of the decrease in switched polarization at low applied fields, in contrast to what is the case for a/c domain walls in tetragonal Pb (Zr 0.2 Ti0.8) O3. © 2010 American Institute of Physics. BT - Journal of Applied Physics DO - 10.1063/1.3392884 LA - eng M1 - 8 N1 - cited By 30 N2 - The switching kinetics in epitaxial (001)-, (110)-, and (111)-oriented BiFeO3 thin films were investigated as a function of applied field and time. It was found that the ferroelectric switching behavior obeys the Kolmogorov-Avrami-Ishibashi theory only in the high field range. The detailed behavior depends on the film orientation. A comparison with standard systems, such as epitaxial Pb (Zr0.2 Ti0.8) O3 films, reveals some similarities as well as some differences. For instance, the presence of 109° and 71° ferroelastic domain walls might be ruled out as the source of the decrease in switched polarization at low applied fields, in contrast to what is the case for a/c domain walls in tetragonal Pb (Zr 0.2 Ti0.8) O3. © 2010 American Institute of Physics. PY - 2010 T2 - Journal of Applied Physics TI - Switching kinetics in epitaxial BiFeO3 thin films VL - 107 SN - 00218979 ER -