TY - JOUR KW - Phase transitions KW - Piezoelectricity KW - Piezoelectric response KW - Piezoelectric property KW - Landau-Devonshire theory KW - Misfit strains KW - Mixed structure KW - Orthorhombic phasis KW - Single domains AU - C.W Huang AU - Y.H Chu AU - Z.H Chen AU - J Wang AU - T Sritharan AU - Q He AU - Ramamoorthy Ramesh AU - L Chen AB - Strain-driven phase transitions and related intrinsic polarization, dielectric, and piezoelectric properties for single-domain films were studied for BiFeO3 using phenomenological Landau-Devonshire theory. A stable and mixed structure between tetragonal and rhombohedral-like (monoclinic) phases is predicted at a compressive misfit strain of um =-0.0382 without an energy barrier. For a tensile misfit strain of um =0.0272, another phase transition between the monoclinic and orthorhombic phases was predicted with sharply high dielectric and piezoelectric responses. © 2010 American Institute of Physics. BT - Applied Physics Letters DO - 10.1063/1.3499658 LA - eng M1 - 15 N1 - cited By 28 N2 - Strain-driven phase transitions and related intrinsic polarization, dielectric, and piezoelectric properties for single-domain films were studied for BiFeO3 using phenomenological Landau-Devonshire theory. A stable and mixed structure between tetragonal and rhombohedral-like (monoclinic) phases is predicted at a compressive misfit strain of um =-0.0382 without an energy barrier. For a tensile misfit strain of um =0.0272, another phase transition between the monoclinic and orthorhombic phases was predicted with sharply high dielectric and piezoelectric responses. © 2010 American Institute of Physics. PY - 2010 T2 - Applied Physics Letters TI - Strain-driven phase transitions and associated dielectric/piezoelectric anomalies in BiFeO3 thin films VL - 97 SN - 00036951 ER -