TY - JOUR AU - E Arenholz AU - G Van Der Laan AU - A Fraile-Rodríguez AU - P Yu AU - Q He AU - Ramamoorthy Ramesh AB - The reduction in symmetry associated with the onset of ferroelectric order in PbZr0.2 Ti0.8 O3 (PZT) thin films leads to a pronounced difference at the Ti L3,2 absorption edges between spectra measured with the x-ray linear polarization perpendicular and parallel to the ferroelectric polarization. We introduce a general method to analyze the observed difference spectra using atomic multiplet calculations. Moreover, we find experimental evidence for structural changes in PZT induced by the reversal of the ferroelectric polarization. © 2010 The American Physical Society. BT - Physical Review B - Condensed Matter and Materials Physics DO - 10.1103/PhysRevB.82.140103 LA - eng M1 - 14 N1 - cited By 28 N2 - The reduction in symmetry associated with the onset of ferroelectric order in PbZr0.2 Ti0.8 O3 (PZT) thin films leads to a pronounced difference at the Ti L3,2 absorption edges between spectra measured with the x-ray linear polarization perpendicular and parallel to the ferroelectric polarization. We introduce a general method to analyze the observed difference spectra using atomic multiplet calculations. Moreover, we find experimental evidence for structural changes in PZT induced by the reversal of the ferroelectric polarization. © 2010 The American Physical Society. PY - 2010 T2 - Physical Review B - Condensed Matter and Materials Physics TI - Probing ferroelectricity in PbZr0.2 Ti0.8 O 3 with polarized soft x rays VL - 82 SN - 10980121 ER -