TY - JOUR KW - Electricity KW - Temperature KW - Room temperature KW - Chemistry KW - Electron microscopy KW - Magnetism KW - Materials testing KW - Electric field KW - Article KW - Circular dichroism KW - Bismuth KW - Ferrite KW - Ferric oxide KW - Electromagnetic field KW - Nanomaterial KW - Ferric ion KW - Ferric Compounds KW - Magnetics KW - Magnetite nanoparticle KW - X-Ray KW - Electron Probe Microanalysis KW - Electromagnetic Phenomena KW - Magnetite Nanoparticles AU - Q He AU - Y.-H Chu AU - J.T Heron AU - S.Y Yang AU - W.I Liang AU - C.Y Kuo AU - H.J Lin AU - P Yu AU - C.W Liang AU - R.J Zeches AU - W.C Kuo AU - J.Y Juang AU - C.T Chen AU - E Arenholz AU - A Scholl AU - Ramamoorthy Ramesh AB - Magnetoelectrics and multiferroics present exciting opportunities for electric-field control of magnetism. However, there are few room-temperature ferromagnetic-ferroelectrics. Among the various types of multiferroics the bismuth ferrite system has received much attention primarily because both the ferroelectric and the antiferromagnetic orders are quite robust at room temperature. Here we demonstrate the emergence of an enhanced spontaneous magnetization in a strain-driven rhombohedral and super-tetragonal mixed phase of BiFeO 3. Using X-ray magnetic circular dichroism-based photoemission electron microscopy coupled with macroscopic magnetic measurements, we find that the spontaneous magnetization of the rhombohedral phase is significantly enhanced above the canted antiferromagnetic moment in the bulk phase, as a consequence of a piezomagnetic coupling to the adjacent tetragonal-like phase and the epitaxial constraint. Reversible electric-field control and manipulation of this magnetic moment at room temperature is also shown. © 2011 Macmillan Publishers Limited. All rights reserved. BT - Nature Communications DO - 10.1038/ncomms1221 LA - eng M1 - 1 N1 - cited By 122 N2 - Magnetoelectrics and multiferroics present exciting opportunities for electric-field control of magnetism. However, there are few room-temperature ferromagnetic-ferroelectrics. Among the various types of multiferroics the bismuth ferrite system has received much attention primarily because both the ferroelectric and the antiferromagnetic orders are quite robust at room temperature. Here we demonstrate the emergence of an enhanced spontaneous magnetization in a strain-driven rhombohedral and super-tetragonal mixed phase of BiFeO 3. Using X-ray magnetic circular dichroism-based photoemission electron microscopy coupled with macroscopic magnetic measurements, we find that the spontaneous magnetization of the rhombohedral phase is significantly enhanced above the canted antiferromagnetic moment in the bulk phase, as a consequence of a piezomagnetic coupling to the adjacent tetragonal-like phase and the epitaxial constraint. Reversible electric-field control and manipulation of this magnetic moment at room temperature is also shown. © 2011 Macmillan Publishers Limited. All rights reserved. PY - 2011 T2 - Nature Communications TI - Electrically controllable spontaneous magnetism in nanoscale mixed phase multiferroics VL - 2 SN - 20411723 ER -