TY - JOUR KW - Nucleation KW - Transmission electron microscopy KW - In situ KW - Electric fields KW - Multiferroics KW - Domain walls KW - Ferroelectric materials KW - Polarization switching KW - Ferroelectricity KW - Ferroelectric domains KW - Scanning transmission electron microscopy KW - Multiferroic materials KW - Ferroelectric films KW - Ferroelastic domains KW - Scanning probes KW - Mesoscopics KW - Bottom electrodes KW - First-order KW - In Situ Study KW - Local electric field KW - Nucleation and growth KW - Nucleation sites KW - Phase-field modeling KW - Scanning transmission electron microscopes KW - Spatially resolved KW - Conductive films KW - Scanning AU - H Chang AU - S.V Kalinin AU - S Yang AU - P Yu AU - S Bhattacharya AU - P.P Wu AU - N Balke AU - S Jesse AU - L.Q Chen AU - Ramamoorthy Ramesh AU - S.J Pennycook AU - A.Y Borisevich AB - Ferroelectric domain nucleation and growth in multiferroic BiFeO 3 films is observed directly by applying a local electric field with a conductive tip inside a scanning transmission electron microscope. The nucleation and growth of a ferroelastic domain and its interaction with pre-existing 71° domain walls are observed and compared with the results of phase-field modeling. In particular, a preferential nucleation site and direction-dependent pinning of domain walls are observed due to slow kinetics of metastable switching in the sample without a bottom electrode. These in situ spatially resolved observations of a first-order bias-induced phase transition reveal the mesoscopic mechanisms underpinning functionality of a wide range of multiferroic materials. © 2011 American Institute of Physics. BT - Journal of Applied Physics DO - 10.1063/1.3623779 LA - eng M1 - 5 N1 - cited By 41 N2 - Ferroelectric domain nucleation and growth in multiferroic BiFeO 3 films is observed directly by applying a local electric field with a conductive tip inside a scanning transmission electron microscope. The nucleation and growth of a ferroelastic domain and its interaction with pre-existing 71° domain walls are observed and compared with the results of phase-field modeling. In particular, a preferential nucleation site and direction-dependent pinning of domain walls are observed due to slow kinetics of metastable switching in the sample without a bottom electrode. These in situ spatially resolved observations of a first-order bias-induced phase transition reveal the mesoscopic mechanisms underpinning functionality of a wide range of multiferroic materials. © 2011 American Institute of Physics. PY - 2011 T2 - Journal of Applied Physics TI - Watching domains grow: In-situ studies of polarization switching by combined scanning probe and scanning transmission electron microscopy VL - 110 SN - 00218979 ER -