TY - JOUR AU - K.J Zhu AU - Gao Liu AU - Y.J Wang AU - J Liu AU - S T Li AU - L.Y Yang AU - S.L Liu AU - H Wang AU - T Xie AB -
An anode material for sodium-ion batteries, Ni-Metal-Organic Frameworks (MOFs)-derived nickel sulfide (NiS2), is first reported. The synthesis strategy involves a novel method in which Ni-based MOFs is fabricated as precursor and then sulfured by sublimed sulfur in solid phase reaction. The as synthesized Ni-MOFs-derived NiS2 shows a hierarchical durian-like nanostructure made of nanoparticles with the diameter of around 10 nm and amorphous carbon with 3 dimensional conductive net skeleton. Moreover, due to the novel hierarchical nanostructure, sodium ions are able to easily insert/extract into/from the active material. As a result, the as synthesized Ni-MOF-derived NiS2 nanostructure electrode exhibits high specific capacity and excellent rate performance. We believe that the hierarchical Ni-MOFs-derived NiS2 nanoparticles will be one of the most promising electrode materials for sodium-ion batteries.
BT - Materials Letters DA - 01/2017 DO - 10.1016/j.matlet.2017.03.087 LA - eng N2 -An anode material for sodium-ion batteries, Ni-Metal-Organic Frameworks (MOFs)-derived nickel sulfide (NiS2), is first reported. The synthesis strategy involves a novel method in which Ni-based MOFs is fabricated as precursor and then sulfured by sublimed sulfur in solid phase reaction. The as synthesized Ni-MOFs-derived NiS2 shows a hierarchical durian-like nanostructure made of nanoparticles with the diameter of around 10 nm and amorphous carbon with 3 dimensional conductive net skeleton. Moreover, due to the novel hierarchical nanostructure, sodium ions are able to easily insert/extract into/from the active material. As a result, the as synthesized Ni-MOF-derived NiS2 nanostructure electrode exhibits high specific capacity and excellent rate performance. We believe that the hierarchical Ni-MOFs-derived NiS2 nanoparticles will be one of the most promising electrode materials for sodium-ion batteries.
PY - 2017 SP - 180 EP - 183 ST - Materials Letters T2 - Materials Letters TI - Metal-Organic Frameworks derived novel hierarchical durian-like nickel sulfide (NiS2) as an anode material for high-performance sodium-ion batteries VL - 197 SN - 0167577X ER -