Rechargeable batteries using LiMn2O4 cathodes are commercially attractive, if the problem of excessive capacity fading can be overcome. The cycling properties of these systems can be improved by partial metal substitution for the Mn. To understand the correlation between electrode performance and composition, Mn, Co, and Ni L-edge XAS and XES spectra of a series of LiMn2-yMeyO4 samples (Me = Co, Ni, Li) were recorded. Cobalt is shown to substitute into the spinel system as Co(III) and nickel as Ni(II). A positive correlation between the cycling stability of the electrode and the covalency of the Mn is observed.
BT - Chemistry of Materials DA - 03/2000 DO - 10.1021/cm990366e IS - 3 N2 -Rechargeable batteries using LiMn2O4 cathodes are commercially attractive, if the problem of excessive capacity fading can be overcome. The cycling properties of these systems can be improved by partial metal substitution for the Mn. To understand the correlation between electrode performance and composition, Mn, Co, and Ni L-edge XAS and XES spectra of a series of LiMn2-yMeyO4 samples (Me = Co, Ni, Li) were recorded. Cobalt is shown to substitute into the spinel system as Co(III) and nickel as Ni(II). A positive correlation between the cycling stability of the electrode and the covalency of the Mn is observed.
PY - 2000 SP - 659 EP - 664 ST - Chem. Mater. T2 - Chemistry of Materials TI - Correlating Electronic Structure with Cycling Performance of Substituted LiMn2O4 Electrode Materials: A Study Using the Techniques of Soft X-ray Absorption and Emission VL - 12 SN - 0897-4756 ER -