TY - JOUR KW - Pyridine KW - Environment KW - Surface KW - Nickel KW - Raman KW - Raman scattering KW - Raman-scattering KW - Scattering KW - Thin KW - Laser KW - Spectroscopy KW - Intensities KW - Intensity KW - Layers KW - Time KW - Sample KW - Samples KW - Alloy KW - Alloys KW - Nm KW - Electrodes KW - Spectra KW - Spectrum KW - Ha KW - Layer KW - Interface KW - L KW - Electrode KW - In situ KW - Interfaces KW - Iron surface KW - Mineral KW - Overlayers KW - Passive film KW - Semiconductor electrode surfaces KW - Sers KW - Silver KW - Silver electrode KW - Spectroelectrochemistry KW - Stainless-steel KW - Steel KW - Surface-enhanced raman KW - Surface-enhanced raman scattering KW - Thickness AU - Lucy J Oblonsky AU - Thomas M Devine AU - Joel W Ager AU - Scott S Perry AU - Xianglei Mao AU - Richard E Russo AB -

Surface-enhanced Raman scattering (SERS) has been detected for pyridine adsorbed onto the surface of thin (average thickness = 2.0 to 8.8 nm), continuous layers of stainless steel that were laser ablated onto roughened electrodes of silver. The experiments were performed on samples immersed in 0.1M KCl + 0.05M pyridine. The SER spectra changed with applied potential, and the intensities of the spectra decreased with increasing thickness of stainless steel. This procedure opens up SERS to the study of electrochemical phenomena at interfaces between alloys and a wide range of aqueous/gaseous environments

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UNIV CALIF BERKELEY,LAWRENCE BERKELEY LAB,BERKELEY,CA 94720

AN - 50 BT - Journal of the Electrochemical Society LA - eng LB - Laser N1 -

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Surface-enhanced Raman scattering (SERS) has been detected for pyridine adsorbed onto the surface of thin (average thickness = 2.0 to 8.8 nm), continuous layers of stainless steel that were laser ablated onto roughened electrodes of silver. The experiments were performed on samples immersed in 0.1M KCl + 0.05M pyridine. The SER spectra changed with applied potential, and the intensities of the spectra decreased with increasing thickness of stainless steel. This procedure opens up SERS to the study of electrochemical phenomena at interfaces between alloys and a wide range of aqueous/gaseous environments

PY - 1994 SP - 3312 EP - 3317 T2 - Journal of the Electrochemical Society TI - Surface-Enhanced Raman-Scattering from Pyridine Adsorbed on Thin-Layers of Stainless-Steel VL - 141 ER -