TY - JOUR
KW - Deposition
KW - Energy
KW - Target
KW - Methane
KW - Nickel
KW - Thin films
KW - Pulsed laser deposition
KW - Evaporation
KW - Experimental
KW - X-ray Diffraction
KW - Ions
KW - Film
KW - Films
KW - Thin
KW - Thin film
KW - Thin-film
KW - Thin films
KW - Laser
KW - Superconducting films
KW - Vaporization
KW - Diffraction
KW - Time
KW - X-Ray
KW - X-ray Diffraction
KW - Ion
KW - Composition
KW - Constant
KW - Process
KW - Structure
KW - Stoichiometry
KW - Calcium
KW - Pulsed laser
KW - Pulsed laser
KW - Targets
KW - Energies
KW - Results
KW - Lattice
KW - Laser deposition
KW - Pulsed laser deposition
KW - Anion
KW - Anions
KW - Binding
KW - Binding-energies
KW - Binding energy
KW - Cations
KW - Chloride
KW - Constants
KW - Conversion
KW - Low-temperature oxydehydrogenation
KW - Nio
KW - Pulsed laser deposition
KW - Selectivity
KW - Sintering
KW - Site
KW - Sodium
KW - Solid solution
KW - Solid-solution
KW - Target composition
AU - Xianglei Mao
AU - Dale L Perry
AU - Richard E Russo
AB - <p>Ca<sub>(1−<em>x</em>)</sub>Ni<sub><em>x</em></sub>O solid-solution films with varying stoichiometry have been prepared by pulsed laser deposition from sintered targets of NiO and CaO. X-ray diffraction data indicate that the films have the structure of sodium chloride. The lattice constants for different stoichiometries vary with film composition. Using the Madelung energy as the binding energy between anions and cations and assuming that nickel and calcium ions are distributed randomly in lattice sites, the lattice constants were calculated and found to compare with experimental results. This study investigated the compositional changes that occur during the target sintering process and the pulsed laser deposition of films. Using these data, a target composition can be prepared to produce Ca<sub>(1−<em>x</em>)</sub>Ni<sub><em>x</em></sub>O thin films with any desired lattice constant.</p>
AD - <p>LAWRENCE BERKELEY LAB,BERKELEY,CA 94720</p>
BT - Journal of Materials Research
C2 - LBNL-34137
DA - 09/1993
DO - 10.1557/JMR.1993.2400
IS - 9
LA - eng
LB - Laser
N1 - <p>LBNL-34137 NOT IN FILE</p>
N2 - <p>Ca<sub>(1−<em>x</em>)</sub>Ni<sub><em>x</em></sub>O solid-solution films with varying stoichiometry have been prepared by pulsed laser deposition from sintered targets of NiO and CaO. X-ray diffraction data indicate that the films have the structure of sodium chloride. The lattice constants for different stoichiometries vary with film composition. Using the Madelung energy as the binding energy between anions and cations and assuming that nickel and calcium ions are distributed randomly in lattice sites, the lattice constants were calculated and found to compare with experimental results. This study investigated the compositional changes that occur during the target sintering process and the pulsed laser deposition of films. Using these data, a target composition can be prepared to produce Ca<sub>(1−<em>x</em>)</sub>Ni<sub><em>x</em></sub>O thin films with any desired lattice constant.</p>
PY - 1993
SP - 2400
EP - 2403
T2 - Journal of Materials Research
TI - Ca(1-X)Nixo Catalytic Thin-Films Prepared by Pulsed-Laser Deposition
VL - 8
ER -