TY - JOUR
KW - Adsorption
KW - Cyclic voltammetry
KW - Platinum
KW - Probe beam deflection
AU - Ederio D Bidoia
AU - Frank R McLarnon
AU - Elton J Cairns
AB - <p>Probe beam deflection (PBD) was used to monitor concentration gradients adjacent to the platinum electrode surface in basic and acidic aqueous media. It was observed that the PBD technique can detect anion adsorption on platinum during a cyclic voltammetry experiment. Also, PBD can measure the potential-dependent extent of adsorption of various anions including ClO<sub>4</sub><sup>−</sup>, H<sub>2</sub>PO<sub>4</sub><sup>−</sup> and Cl<sup>−</sup> on the Pt electrode surface.</p>
BT - Journal of Electroanalytical Chemistry
DA - 02/2000
DO - 10.1016/S0022-0728(00)00003-6
IS - 1
LA - eng
LB - Electrochem
N2 - <p>Probe beam deflection (PBD) was used to monitor concentration gradients adjacent to the platinum electrode surface in basic and acidic aqueous media. It was observed that the PBD technique can detect anion adsorption on platinum during a cyclic voltammetry experiment. Also, PBD can measure the potential-dependent extent of adsorption of various anions including ClO<sub>4</sub><sup>−</sup>, H<sub>2</sub>PO<sub>4</sub><sup>−</sup> and Cl<sup>−</sup> on the Pt electrode surface.</p>
PY - 2000
SP - 75
EP - 80
T2 - Journal of Electroanalytical Chemistry
TI - Investigation of anion adsorption on platinum electrodes in aqueous media by probe beam deflection
VL - 482
ER -