@article{bibcite_36753,
  author = {Tingting Zhai and Hao Wang and Sarah R Beaudoin and Ran Zhang and Minkyoung Kwak and Shujin Hou and Zhengxiao Guo and Shannon W Boettcher},
  title = {Perovskite Catalysts for Pure-Water-Fed Anion-Exchange-Membrane Electrolyzer Anodes: Co-design of Electrically Conductive Nanoparticle Cores and Active Surfaces},
  abstract = {<p>Anion-exchange-membrane water electrolyzers (AEMWEs) are a possible low-capital-expense, efficient, and scalable hydrogen-production technology with inexpensive hardware, earth-abundant catalysts, and pure water. However, pure-water-fed AEMWEs remain at an early stage of development and suffer from inferior performance compared with proton-exchange-membrane water electrolyzers (PEMWEs). One challenge is to develop effective non-platinum-group-metal (non-PGM) anode catalysts and electrodes in pure-water-fed AEMWEs. We show how LaNiO<sub>3</sub>-based perovskite oxides can be tuned by cosubstitution on both A- and B-sites to simultaneously maintain high metallic electrical conductivity along with a degree of surface reconstruction to expose a stable Co-based active catalyst. The optimized perovskite, Sr<sub>0.1</sub>La<sub>0.9</sub>Co<sub>0.5</sub>Ni<sub>0.5</sub>O<sub>3</sub>, yielded pure-water AEMWEs operating at 1.97 V at 2.0 A cm<sup>{\textendash}2</sup> at 70 {\textdegree}C with a pure-water feed, thus illustrating the utility of the catalyst design principles.</p><p>\&nbsp;</p>},
  year = {2025},
  booktitle = {Journal of the American Chemical Society},
  journal = {Journal of the American Chemical Society},
  series = {Journal of the American Chemical Society},
  volume = {147},
  pages = {15448-15458},
  month = {07/05/2025},
  institution = {American Chemical Society (ACS)},
  publisher = {American Chemical Society (ACS)},
  issn = {0002-7863, 1520-5126},
  url = {https://doi.org/10.1021/jacs.5c01621},
  doi = {10.1021/jacs.5c01621},
}